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1 article(s) from Henkel, Philip

Selectivity control towards CO versus H₂ for photo-driven CO₂ reduction with a novel Co(II) catalyst

Lisa-Lou Gracia,
Philip Henkel,
Olaf Fuhr and
Claudia Bizzarri

Beilstein J. Org. Chem. 2023, 19, 1766–1775, doi:10.3762/bjoc.19.129

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Figure 1: Chemical structures of the molecular components used in this work: Co(II) complex 1 as the novel ca...

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Figure 2: ORTEP drawing of crystal polymorph 1a (left) and 1b (right), shown at the 50% probability level. Hy...

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Figure 3: UV–vis absorbance of complex 1 in DMA. Inset: zoom-in of the 500–800 nm range to visualize the low-...

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Figure 4: Cyclic voltammetry of complex 1 in 0.1 M TBAPF₆ solution of (a) DMA and (b) DMA/TEOA 5:1 (v/v). Bla...

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Figure 5: Time evolution of CO (blue squares) and H₂ (red triangles) with the power functional fitting (blue ...

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Scheme 1: Proposed mechanism for the photoinduced reduction of carbon dioxide with the system presented in th...

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Published 17 Nov 2023

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Selectivity control towards CO versus H2 for photo-driven CO2 reduction with a novel Co(II) catalyst

Selectivity control towards CO versus H₂ for photo-driven CO₂ reduction with a novel Co(II) catalyst